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Enantioselective Total Synthesis of (−)-Acylfulvene and (−)-Irofulven

[Image: see text] We report our full account of the enantioselective total synthesis of (−)-acylfulvene (1) and (−)-irofulven (2), which features metathesis reactions for the rapid assembly of the molecular framework of these antitumor agents. We discuss (1) the application of an Evans’ Cu-catalyzed...

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Detalhes bibliográficos
Main Authors: Siegel, Dustin S., Piizzi, Grazia, Piersanti, Giovanni, Movassaghi, Mohammad
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2805080/
https://ncbi.nlm.nih.gov/pubmed/19938810
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo901926z
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