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Enantioselective Total Synthesis of (+)-Cassiol
[Image: see text] An enantioselective total synthesis of (+)-cassiol is reported. The complex derived from Pd(2)(pmdba)(3) and enantiopure t-BuPHOX ligand catalyzes enantioconvergent decarboxylative alkylation to generate the quaternary carbon stereocenter at an early stage. The overall synthetic st...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2707596/ https://ncbi.nlm.nih.gov/pubmed/19093836 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802410t |
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