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A Cu-Catalyzed, pH-Neutral, Aerobic, Room Temperature Construction of High Enantiopurity Peptidyl Ketones from Peptidic S-Acylthiosalicylamides
[Image: see text] Described herein is a Cu-catalyzed transformation of peptidic thiol esters and boronic acids into peptidyl ketones that takes place at room temperature in DMF or in DMF/H(2)O open to air and uses only catalytic quantities of a Cu carboxylate to mediate the reaction. This aerobic tr...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2790066/ https://ncbi.nlm.nih.gov/pubmed/19145620 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200804524 |
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