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Synthesis of High Enantiopurity N-Protected α-Amino Ketones by Thiol Ester-Organostannane Cross-Coupling using pH-Neutral Conditions

[Image: see text] An efficient synthesis of high enantiopurity N-protected α-amino ketones is described. Complementing other studies using boronic acids and thiol esters, this Cu(I) diphenylphosphinate (CuDPP)-mediated, palladium-catalyzed coupling of α-amino thiol esters with aryl, heteroaryl, ally...

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Autores principales: Li, Hao, Yang, Hao, Liebeskind, Lanny S.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2008
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2654251/
https://ncbi.nlm.nih.gov/pubmed/18759432
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol8018456
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