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C—H Bond Cleavage with Reductants: Re-Investigating the Reactivity of Monomeric Mn(III/IV)—Oxo Complexes and the Role of Oxo Ligand Basicity
The thermodynamic properties of structurally similar Mn(III) and Mn(IV) complexes have been re-investigated to understand their reactivity with substrates having C—H bonds. The complexes have the general formula, [MnH(3)buea(O)](n-), where [H(3)buea](3-) is the tripodal ligand, tris[(N’-tert-butylur...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2787892/ https://ncbi.nlm.nih.gov/pubmed/19196005 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja8100825 |
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