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Autoxidation of Salvinorin A under Basic Conditions
Treatment of salvinorin A (1a) with KOH in MeOH gave the enedione 3, for which the dienone structure 7 was recently proposed. Also isolated, after methylation, were the seco-triesters 4a—c. A mechanism for this unusual series of autoxidations is proposed. Surprisingly, 4a showed weak affinity at the...
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| Главные авторы: | , , , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2005
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2778035/ https://ncbi.nlm.nih.gov/pubmed/16292839 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo051813e |
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