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Excess Substrate is a Spectator Ligand in a Rhodium-Catalyzed Asymmetric [2+2+2] Cycloaddition of Alkenyl Isocyanates with Tolanes

[Image: see text] Excess substrate has been identified as an unintended spectator ligand affecting enantioselectivity in the [2+2+2] cycloaddition of alkenyl isocyanates with tolanes. Replacement of excess substrate with an exogenous additive affords products with consistent and higher ee’s. The inc...

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Detaylı Bibliyografya
Asıl Yazarlar: Oinen, Mark Emil, Yu, Robert T., Rovis, Tomislav
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2009
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC2777613/
https://ncbi.nlm.nih.gov/pubmed/19803471
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol9020805
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