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A Relay Ring-Closing Metathesis Synthesis of Dihydrooxasilines, Precursors of (Z)-Iodo Olefins

[Image: see text] A convenient Grubbs II metathesis provides dihydrooxasilines by relay RCM (RRCM). Dihydrooxasilines undergo ring opening to give Z-vinyl silanes. These can then be converted to Z-vinyl iodides. This sequence provides a short, high yield, and convenient route to trisubstituted Z-vin...

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Autors principals: Xie, Qiuzhe, Denton, Richard W., Parker, Kathlyn A.
Format: Artigo
Idioma:Inglês
Publicat: 2008
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2765515/
https://ncbi.nlm.nih.gov/pubmed/19006314
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802063h
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