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Synthesis of 2H-Chromenes via Hydrazine-Catalyzed Ring-Closing Carbonyl-Olefin Metathesis

The catalytic ring-closing carbonyl-olefin metathesis (RCCOM) of O-allyl salicylaldehydes to form 2H-chromenes is described. The method utilizes a [2.2.1]-bicyclic hydrazine catalyst and operates via a [3+2]/retro-[3+2] metathesis manifold. The nature of the allyl substitution pattern was found to b...

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Detalhes bibliográficos
Publicado no:ACS Catal
Main Authors: Zhang, Yunfei, Jermaks, Janis, MacMillan, Samantha N., Lambert, Tristan H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8172096/
https://ncbi.nlm.nih.gov/pubmed/34084650
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.9b03656
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