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The Total Synthesis of Irciniastatin A (Psymberin)
[Image: see text] The total synthesis of (+)-iriciniastatin A (psymberin) is reported in 19 steps and 6% overall yield. Key reactions include a highly convergent enolsilane-oxocarbenium ion union to generate the C8-C25 fragment and a late stage coupling of a hemiaminal and acid chloride to complete...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2752752/ https://ncbi.nlm.nih.gov/pubmed/19670853 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol901655e |
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