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Total Synthesis of (+)-Irciniastatin A (a.k.a. Psymberin) and (−)-Irciniastatin B
A unified synthetic strategy to access (+)-irciniastatin A (a.k.a. psymberin) and (−)- irciniastatin B, two cytotoxic secondary metabolites, has been achieved. Highlights of the convergent strategy comprise a boron-mediated aldol union to set the C(15)–C(17) syn-syn triad, reagent control to set the...
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| Main Authors: | , , , , |
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| Formáid: | Artigo |
| Teanga: | Inglês |
| Foilsithe: |
2013
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| Ábhair: | |
| Rochtain Ar Líne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3651581/ https://ncbi.nlm.nih.gov/pubmed/23510264 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo400260m |
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