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Total Synthesis of (+)-Psymberin (Irciniastatin A): Catalytic Reagent Control as the Strategic Cornerstone
[Image: see text] An effective total synthesis of the marine sponge cytotoxin (+)-psymberin [irciniastatin (1)] has been achieved. Highlights of the strategy include a Diels-Alder reaction between a bissiloxy diene and an allene to construct the aromatic ring, a boron-mediated aldol to elaborate the...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2008
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2750869/ https://ncbi.nlm.nih.gov/pubmed/19072197 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802466t |
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