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The Chiral Crown Conformation of Rh(2)(S-PTTL)(4): Enantioselective Cyclopropanation with α-Alkyl-α-diazoesters
[Image: see text] Herein, we provide crystallographic and computational evidence that Hashimoto’s Rh(2)(S-PTTL)(4) catalyst adopts a “chiral crown” conformation with a reactive chiral face and an unreactive achiral face. In Rh(2)(S-PTTL)(4), all four t-butyl groups are aligned on the same face of th...
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| 主要な著者: | , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2009
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2738984/ https://ncbi.nlm.nih.gov/pubmed/19469571 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9026852 |
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