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Rh(2)(S-PTTL)(3)TPA—A Mixed Ligand Dirhodium(II) Catalyst for Enantioselective Reactions of α-Alkyl-α-Diazoesters
Herein we report the synthesis of the mixed ligand paddlewheel complex dirhodium(II) tris[N-phthaloyl-(S)-tert-leucinate] triphenylacetate, Rh(2)(S-PTTL)(3)TPA, the structure of which bears similarity to the chiral crown complex Rh(2)(S-PTTL)(4). Rh(2)(S-PTTL)(3)TPA engages substrate classes (alipha...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3486924/ https://ncbi.nlm.nih.gov/pubmed/23125912 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C2SC01134D |
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