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Synthesis of conformationally locked carbocyclic 1,3-diazepinone nucleosides as inhibitors of cytidine deaminase

We synthesized a series of carbocyclic nucleoside inhibitors of cytidine deaminase (CDA) based on a seven-membered 1,3-diazepin-2-one moiety. In the key step, the seven-membered ring was formed by a ringclosing- metathesis reaction. Therefore, the bis-allylurea moiety had to be protected by benzoyla...

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Autors principals: Ludek, Olaf R., Schroeder, Gottfried K., Wolfenden, Richard, Marquez, Victor E.
Format: Artigo
Idioma:Inglês
Publicat: 2008
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2730941/
https://ncbi.nlm.nih.gov/pubmed/18776552
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1093/nass/nrn333
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