טוען...
Crystal Structures of Fe(2+) Dioxygenase Superoxo, Alkylperoxo, and Bound Product Intermediates
We report the structures of three intermediates in the O(2) activation and insertion reactions of an extradiol ring-cleaving dioxygenase. A crystal of Fe(2+)-containing homoprotocatechuate 2,3-dioxygenase was soaked in the slow substrate 4-nitrocatechol in a low O(2) atmosphere. The X-ray crystal st...
שמור ב:
| Main Authors: | , |
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| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2007
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2720167/ https://ncbi.nlm.nih.gov/pubmed/17446402 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.1134697 |
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