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Crystal Structures of Fe(2+) Dioxygenase Superoxo, Alkylperoxo, and Bound Product Intermediates
We report the structures of three intermediates in the O(2) activation and insertion reactions of an extradiol ring-cleaving dioxygenase. A crystal of Fe(2+)-containing homoprotocatechuate 2,3-dioxygenase was soaked in the slow substrate 4-nitrocatechol in a low O(2) atmosphere. The X-ray crystal st...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2720167/ https://ncbi.nlm.nih.gov/pubmed/17446402 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.1134697 |
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