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Intermediate in the O–O Bond Cleavage Reaction of an Extradiol Dioxygenase
The reactive oxy-intermediate of the catalytic cycle of extradiol aromatic ring-cleaving dioxygenases is formed by binding the catecholic substrate and O(2) in adjacent ligand positions of the active site metal (usually Fe(II)). This intermediate and the following Fe(II)-alkylperoxo intermediate res...
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| Main Authors: | , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2008
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2629449/ https://ncbi.nlm.nih.gov/pubmed/18826259 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi801459q |
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