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What are the consequences of freezing the anomeric effect in nucleosides?
The consequences of freezing the orientation of the oxygen’s lone pair orbitals —which determines whether the anomeric effect is operative or not— were studied theoretically and experimentally in two oxobicyclo-[3.1.0]hexane nucleosides (1 and 2). The results showed significant differences in the pr...
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| Main Authors: | , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2700545/ https://ncbi.nlm.nih.gov/pubmed/18776494 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1093/nass/nrn275 |
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