Using conformationally locked nucleosides to calibrate the anomeric effect: Implications for glycosyl bond stability

Steric and electronic parameters such as the anomeric effect (AE) and gauche effect play significant roles in steering the North ⇆ South equilibrium of nucleosides in solution. Two isomeric oxa-bicyclo[3.1.0]hexane nucleosides that are conformationally locked in either the North or the South conform...

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Main Authors: Moon, Hyung Ryong, Siddiqui, Maqbool A., Sun, Guangyu, Filippov, Igor V., Landsman, Nicholas A., Lee, Yi-Chien, Adams, Kristie M., Barchi, Joseph J., Deschamps, Jeffrey R., Nicklaus, Marc C., Kelley, James A., Marquez, Victor E.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2967253/
https://ncbi.nlm.nih.gov/pubmed/21052524
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2010.06.044
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