Mössbauer and DFT Study of the Ferromagnetically Coupled Diiron(IV) Precursor to a Complex with an Fe(IV)(2)O(2) Diamond Core

Recently we reported the reaction of the (μ-oxo)diiron(III) complex 1 ([Fe(III)(2)(μ-O)(μ-O(2)H(3))(L)(2)](3+), L = tris(3,5-dimethyl-4-methoxypyridyl-2-methyl)amine) with 1 equivalent of H(2)O(2) to yield a diiron(IV) intermediate, 2 (Xue, Fiedler, Martinho, Münck, and Que, Proc. Natl. Acad. Sci. U...

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Main Authors: Martinho, Marlène, Xue, Genqiang, Fiedler, Adam T., Que, Lawrence, Bominaar, Emile L., Münck, Eckard
格式: Artigo
語言:Inglês
出版: 2009
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Article
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC2675788/
https://ncbi.nlm.nih.gov/pubmed/19338307
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja8098917
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