Structural, EPR and Mössbauer Characterization of (μ-Alkoxo)(μ-Carboxylato)Diiron(II,III) Model Complexes for the Active Sites of Mixed-valent Diiron Enzymes

To obtain structural and spectroscopic models for the diiron(II,III) centers in the active sites of diiron enzymes, the (μ-alkoxo)(μ-carboxylato)diiron(II,III) complexes [Fe(II)Fe(III)(N-Et-HPTB)(O(2)CPh)(NCCH(3))(2)](ClO(4))(3) (1) and [Fe(II)Fe(III)(N-Et-HPTB)(O(2)CPh) (Cl)(HOCH(3))](ClO(4))(2) (2...

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主要な著者: Li, Feifei, Chakrabarti, Mrinmoy, Dong, Yanhong, Kauffmann, Karl, Bominaar, Emile L., Münck, Eckard, Que, Lawrence
フォーマット: Artigo
言語:Inglês
出版事項: 2012
主題:
Article
オンライン･アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3298377/
https://ncbi.nlm.nih.gov/pubmed/22360600
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic2021726
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