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Autocatalysis in Lithium Diisopropylamide-MediatedOrtholithiations
Ortholithiation of 3-fluorophenyl-N,N-diisopropyl carbamate by lithium diisopropylamide (LDA) in THF at −78 °C affords unusual rate behavior including linear decays of the carbamate, delayed formation of LDA-aryllithium mixed dimers, and evidence of autocatalysis. A mechanistic model in conjunction...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2008
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2643095/ https://ncbi.nlm.nih.gov/pubmed/19053473 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja807331k |
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