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Regioselective Lithium Diisopropylamide-Mediated Ortholithiation of 1-Chloro-3-(trifluoromethyl)benzene: Role of Autocatalysis, Lithium Chloride Catalysis, and Reversibility
Ortholithiation of 1-chloro-3-(trifluoromethyl)benzene with lithium diisopropylamide (LDA) in tetrahydrofuran at −78 °C displays characteristics of reactions in which aggregation events are rate limiting. Metalation with lithium chloride-free LDA involves a rate-limiting deaggregation via dimer-base...
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| Main Authors: | , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2011
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3102585/ https://ncbi.nlm.nih.gov/pubmed/21500823 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja200906z |
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