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Lithium Diisopropylamide-Mediated Ortholithiations: Lithium Chloride Catalysis
Ortholithiations of a range of arenes mediated by lithium diisopropylamide (LDA) in THF at -78 °C reveal substantial accelerations by as little as 0.5 mol % LiCl (relative to LDA). Substrate dependencies suggest a specific range of reactivity within which the LiCl catalysis is optimal. Standard prot...
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| Hlavní autoři: | , , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2009
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2765536/ https://ncbi.nlm.nih.gov/pubmed/19191711 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo802713y |
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