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Asymmetric, Organocatalytic, 3-Step Synthesis of γ-Hydroxy-(E)-α-β-Unsaturated Sulfones and Esters

[Image: see text] Efficient and enantiocontrolled synthesis of γ-hydroxy-α,β-unsaturated sulfones and esters are reported through the reaction of enantioenriched α-selenyl aldehydes with EWG-stabilized carbanions and then a one pot selenide oxidation, in situ epoxide formation, and final in situ epo...

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Detalhes bibliográficos
Main Authors: Petersen, Kimberly S., Posner, Gary H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2628291/
https://ncbi.nlm.nih.gov/pubmed/18811178
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol8020513
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