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Regiospecific Hydration of γ-Hydroxy-α,β-Acetylenic Esters: A Novel Asymmetric Synthesis of Tetronic Acids
[Image: see text] The optically active γ-hydroxy-α,β-acetylenic esters are obtained from the enantioselective reaction of methyl propiolate with both aliphatic and aromatic aldehydes. These compounds can undergo regiospecific hydration in the presence of Zeise’s dimer, [PtCl(2)(C(2)H(4))](2), to gen...
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| Main Authors: | , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2006
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2597458/ https://ncbi.nlm.nih.gov/pubmed/16671771 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol060377v |
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