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Atomic detail of chemical transformation at the transition state of an enzymatic reaction

Transition path sampling (TPS) has been applied to the chemical step of human purine nucleoside phosphorylase (PNP). The transition path ensemble provides insight into the detailed mechanistic dynamics and atomic motion involved in transition state passage. The reaction mechanism involves early loss...

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Main Authors: Saen-oon, Suwipa, Quaytman-Machleder, Sara, Schramm, Vern L., Schwartz, Steven D.
Format: Artigo
Jezik:Inglês
Izdano: National Academy of Sciences 2008
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2575456/
https://ncbi.nlm.nih.gov/pubmed/18946041
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0808413105
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