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Atomic detail of chemical transformation at the transition state of an enzymatic reaction

Transition path sampling (TPS) has been applied to the chemical step of human purine nucleoside phosphorylase (PNP). The transition path ensemble provides insight into the detailed mechanistic dynamics and atomic motion involved in transition state passage. The reaction mechanism involves early loss...

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Bibliographic Details
Main Authors: Saen-oon, Suwipa, Quaytman-Machleder, Sara, Schramm, Vern L., Schwartz, Steven D.
Format: Artigo
Language:Inglês
Published: National Academy of Sciences 2008
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2575456/
https://ncbi.nlm.nih.gov/pubmed/18946041
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0808413105
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