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Radical Intermediates in the Catalytic Oxidation of Hydrocarbons by Bacterial and Human Cytochrome P450 Enzymes

Cytochromes P450(cam) and P450(BM3) oxidize α- and β-thujone into multiple products, including 7-hydroxy-α-(or β-)thujone, 7,8-dehydro-α-(or β-)thujone, 4-hydroxy-α-(or β-)thujone, 2-hydroxy α-(or β-)thujone, 5-hydroxy-5-isopropyl-2-methyl-2-cyclohexen-1-one, 4,10-dehydrothujone, and carvacrol. Quan...

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Detalhes bibliográficos
Main Authors: Jiang, Yongying, He, Xiang, Ortiz de Montellano, Paul R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2566308/
https://ncbi.nlm.nih.gov/pubmed/16401082
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi051840z
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