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Spectroscopic and Quantum Chemical Studies on low-spin Fe(IV)=O complexes: Fe-O bonding and its contributions to reactivity

High valent Fe(IV)=O species are key intermediates in the catalytic cycles of many mononuclear non-heme iron enzymes and have been structurally defined in model systems. Variable temperature magnetic circular dichroism (VT-MCD) spectroscopy has been used to evaluate the electronic structures and in...

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Bibliografiske detaljer
Main Authors: Decker, Andrea, Rohde, Jan-Uwe, Klinker, Eric J., Wong, Shaun D., Que, Lawrence, Solomon, Edward I.
Format: Artigo
Sprog:Inglês
Udgivet: 2007
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2547486/
https://ncbi.nlm.nih.gov/pubmed/18052249
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja074900s
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