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Spectroscopic and Quantum Chemical Studies on low-spin Fe(IV)=O complexes: Fe-O bonding and its contributions to reactivity
High valent Fe(IV)=O species are key intermediates in the catalytic cycles of many mononuclear non-heme iron enzymes and have been structurally defined in model systems. Variable temperature magnetic circular dichroism (VT-MCD) spectroscopy has been used to evaluate the electronic structures and in...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2007
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2547486/ https://ncbi.nlm.nih.gov/pubmed/18052249 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja074900s |
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