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Differential Sensing of Protein Influences by NO and CO Vibrations in Heme Adducts

Heme proteins bind the gaseous ligands XO (X = C, N, O) via backbonding from Fe d(π) electrons. Backbonding is modulated by distal interactions of the bound ligand with the surrounding protein and by variations in the strength of the trans proximal ligand. Vibrational modes associated with FeX and X...

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Hlavní autoři: Ibrahim, Mohammed, Xu, Changliang, Spiro, Thomas G.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2006
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2530899/
https://ncbi.nlm.nih.gov/pubmed/17177434
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja064859d
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