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Differential Sensing of Protein Influences by NO and CO Vibrations in Heme Adducts
Heme proteins bind the gaseous ligands XO (X = C, N, O) via backbonding from Fe d(π) electrons. Backbonding is modulated by distal interactions of the bound ligand with the surrounding protein and by variations in the strength of the trans proximal ligand. Vibrational modes associated with FeX and X...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2006
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2530899/ https://ncbi.nlm.nih.gov/pubmed/17177434 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja064859d |
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