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Ambidentate H-bonding by heme-bound NO: structural and spectral effects of -O vs -N H-bonding

Resonance Raman studies have uncovered puzzling complexities in the structures of NO adducts of heme proteins. Although CO adducts of heme proteins obey well-behaved anti-correlations between Fe-C and C-O stretching frequencies, which reflect changes in backbonding induced by distal H-bonding residu...

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Detalhes bibliográficos
Main Authors: Xu, Changliang, Spiro, Thomas G.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2585551/
https://ncbi.nlm.nih.gov/pubmed/18274790
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00775-008-0349-8
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