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Ambidentate H-bonding of NO and O(2) in Heme Proteins

The affinity and reactivity of the gaseous molecules CO, NO and O(2) (XO) in heme protein adducts are controlled by secondary interactions, especially by H-bonds donated from distal protein residues. Vibrational spectroscopy, supported by DFT modeling, has revealed that for NO and O(2), but not for...

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Detalhes bibliográficos
Main Authors: Spiro, Thomas G., Soldatova, Alexandra V.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3463650/
https://ncbi.nlm.nih.gov/pubmed/22824153
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jinorgbio.2012.05.013
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