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Electronic Structure and Ligand Vibrations in FeNO, CoNO and FeOO Porphyrin Adducts
The gaseous ligands, CO, NO and O(2) interact with the Fe ion in heme proteins largely via backbonding of Fe electrons to the π* orbitals of the XO (X = C, N, O) ligands. In these FeXO adducts, the Fe–X stretching frequency varies inversely with the X–O stretching frequency, since increased backbond...
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| Asıl Yazarlar: | , , |
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| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
2013
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3766410/ https://ncbi.nlm.nih.gov/pubmed/23763617 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic400364x |
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