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Electronic Structure and Ligand Vibrations in FeNO, CoNO and FeOO Porphyrin Adducts
The gaseous ligands, CO, NO and O(2) interact with the Fe ion in heme proteins largely via backbonding of Fe electrons to the π* orbitals of the XO (X = C, N, O) ligands. In these FeXO adducts, the Fe–X stretching frequency varies inversely with the X–O stretching frequency, since increased backbond...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3766410/ https://ncbi.nlm.nih.gov/pubmed/23763617 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic400364x |
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