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Two-Photon Photochemical Generation of Reactive Enediyne
p-Quinoid cyclopropenone-containing enediyne precursor (1) has been synthesized by mono-cyclopropanation of one of the triple bonds in p-dimethoxy substituted 3,4-benzocyclodeca-1,5-diyne followed by oxidative demethylation. Cyclopropenone 1 is stable up to 90°C but readily produces reactive enediyn...
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| Autori principali: | , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2006
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2528024/ https://ncbi.nlm.nih.gov/pubmed/16958537 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo061285m |
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