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Triggering of the Bergman Cyclization by Photochemical Ring Contraction. Facile Cycloaromatization of Benzannulated Cyclodeca-3,7-diene-1,5-diynes
[Image: see text] Eleven-membered ring enediyne 1, which incorporates α-diazo-β-diketone moiety, undergoes efficient light-induced ring contraction to produce two isomeric ten-membered ring enediyne compounds. The latter undergo spontaneous facile Bergman cyclization at or below room temperature. In...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2543122/ https://ncbi.nlm.nih.gov/pubmed/17352468 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja064470q |
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