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Highly substituted benzannulated cyclooctanol derivatives by samarium diiodide-induced cyclizations

A series of γ-oxo esters suitably substituted with various styrene subunits was subjected to samarium diiodide-induced 8-endo-trig cyclizations. Efficacy, regioselectivity and stereoselectivity of these reactions via samarium ketyls strongly depend on the substitution pattern of the attacked alkene...

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Bibliografiske detaljer
Main Authors: Saadi, Jakub, Brüdgam, Irene, Reissig, Hans-Ulrich
Format: Artigo
Sprog:Inglês
Udgivet: Beilstein-Institut 2010
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3028607/
https://ncbi.nlm.nih.gov/pubmed/21283559
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.6.141
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