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Photochemical Generation and Reactivity of the Major Hydroxyl Radical Adduct of Thymidine
[Image: see text] 5,6-Dihydro-5-hydroxythymidin-6-yl radical (1), the major reactive intermediate resulting from hydroxyl radical addition to C5 of the pyrimidine is produced via 350 nm photolysis of a 2,5-dimethylphenylsulfide precursor (2). Competition between O(2) and thiol for 1 suggests that th...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3366351/ https://ncbi.nlm.nih.gov/pubmed/22616940 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol301109z |
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