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Independent Photochemical Generation and Reactivity of Nitrogen-Centered Purine Nucleoside Radicals From Hydrazines
Photochemical precursors that produce dA• and dG(N(2)-H)• are needed to investigate their reactivity. The synthesis of two 1,1-diphenylhydrazines (1, 2) and their use as photochemical sources of dA• and dG(N(2)-H)• is presented. Trapping studies indicate production of these radicals with good fideli...
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| Veröffentlicht in: | Org Lett |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2017
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5711525/ https://ncbi.nlm.nih.gov/pubmed/29125775 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b03368 |
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