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Photochemical Control of DNA Structure via Radical Disproportionation
Photolysis of an aryl sulfide containing 5,6-dihydropyrimidine (1) at 350 nm produces high yields of thymidine and products resulting from trapping of 5,6-dihydrothymidin-5-yl radical by O(2) or thiols. Thymidine is believed to result from disproportionation of the radical pair originally generated...
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| 主要な著者: | , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2013
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3807129/ https://ncbi.nlm.nih.gov/pubmed/23940105 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cbic.201300369 |
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