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Ring-Closing Metathesis for the Synthesis of a Highly G-Quadruplex Selective Macrocyclic Hexaoxazole Having Enhanced Cytotoxic Potency

The synthesis of a 24-membered macrocyclic hexaoxazole via ring-closing metathesis is described. The target compound selectively stabilizes G-quadruplex DNA with no detectable stabilization of duplex DNA. An MTT cytotoxicity assay indicated that this unsaturated macrocyclic hexaoxazole exhibits sign...

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Detalhes bibliográficos
Main Authors: Satyanarayana, Mavurapu, Rzuczek, Suzanne G., LaVoie, Edmond J., Pilch, Daniel S., Liu, Angela, Liu, Leory F., Rice, Joseph E.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2518403/
https://ncbi.nlm.nih.gov/pubmed/18515097
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bmcl.2008.05.032
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