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Terminal Hydride in [FeFe]-Hydrogenase Model Has Lower Potential for H(2) Production Than the Isomeric Bridging Hydride

Protonation of the symmetrical tetraphosphine complexes Fe(2)(S(2)C(n)H(2)(n))(CO)(2)(dppv)(2) afforded the corresponding terminal hydrides, establishing that even symmetrical diiron(I) dithiolates undergo protonation at terminal sites. The terminal hydride [HFe(2)(S(2)C(3)H(6))(CO)(2)(dppv)(2)](+)...

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Bibliografiske detaljer
Main Authors: Barton, Bryan E., Rauchfuss, Thomas B.
Format: Artigo
Sprog:Inglês
Udgivet: 2008
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2423930/
https://ncbi.nlm.nih.gov/pubmed/18333613
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic800030y
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