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Terminal Hydride in [FeFe]-Hydrogenase Model Has Lower Potential for H(2) Production Than the Isomeric Bridging Hydride
Protonation of the symmetrical tetraphosphine complexes Fe(2)(S(2)C(n)H(2)(n))(CO)(2)(dppv)(2) afforded the corresponding terminal hydrides, establishing that even symmetrical diiron(I) dithiolates undergo protonation at terminal sites. The terminal hydride [HFe(2)(S(2)C(3)H(6))(CO)(2)(dppv)(2)](+)...
Tallennettuna:
| Päätekijät: | , |
|---|---|
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2008
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2423930/ https://ncbi.nlm.nih.gov/pubmed/18333613 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic800030y |
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