A synthetic host-guest system achieves avidin-biotin affinity by overcoming enthalpy–entropy compensation

The molecular host cucurbit[7]uril forms an extremely stable inclusion complex with the dicationic ferrocene derivative bis(trimethylammoniomethyl)ferrocene in aqueous solution. The equilibrium association constant for this host-guest pair is 3 × 10(15) M(−1) (K(d) = 3 × 10(−16) M), equivalent to th...

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Detalhes bibliográficos
Main Authors: Rekharsky, Mikhail V., Mori, Tadashi, Yang, Cheng, Ko, Young Ho, Selvapalam, N., Kim, Hyunuk, Sobransingh, David, Kaifer, Angel E., Liu, Simin, Isaacs, Lyle, Chen, Wei, Moghaddam, Sarvin, Gilson, Michael K., Kim, Kimoon, Inoue, Yoshihisa
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2007
Assuntos:
Biological Sciences
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2410071/
https://ncbi.nlm.nih.gov/pubmed/18093926
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0706407105
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