A synthetic host-guest system achieves avidin-biotin affinity by overcoming enthalpy–entropy compensation

The molecular host cucurbit[7]uril forms an extremely stable inclusion complex with the dicationic ferrocene derivative bis(trimethylammoniomethyl)ferrocene in aqueous solution. The equilibrium association constant for this host-guest pair is 3 × 10(15) M(−1) (K(d) = 3 × 10(−16) M), equivalent to th...

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Bibliografiska uppgifter
Huvudupphovsmän: Rekharsky, Mikhail V., Mori, Tadashi, Yang, Cheng, Ko, Young Ho, Selvapalam, N., Kim, Hyunuk, Sobransingh, David, Kaifer, Angel E., Liu, Simin, Isaacs, Lyle, Chen, Wei, Moghaddam, Sarvin, Gilson, Michael K., Kim, Kimoon, Inoue, Yoshihisa
Materialtyp: Artigo
Språk:Inglês
Publicerad: National Academy of Sciences 2007
Ämnen:
Biological Sciences
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC2410071/
https://ncbi.nlm.nih.gov/pubmed/18093926
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0706407105
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