A synthetic host-guest system achieves avidin-biotin affinity by overcoming enthalpy–entropy compensation

The molecular host cucurbit[7]uril forms an extremely stable inclusion complex with the dicationic ferrocene derivative bis(trimethylammoniomethyl)ferrocene in aqueous solution. The equilibrium association constant for this host-guest pair is 3 × 10(15) M(−1) (K(d) = 3 × 10(−16) M), equivalent to th...

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Autori principali: Rekharsky, Mikhail V., Mori, Tadashi, Yang, Cheng, Ko, Young Ho, Selvapalam, N., Kim, Hyunuk, Sobransingh, David, Kaifer, Angel E., Liu, Simin, Isaacs, Lyle, Chen, Wei, Moghaddam, Sarvin, Gilson, Michael K., Kim, Kimoon, Inoue, Yoshihisa
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Academy of Sciences 2007
Soggetti:
Biological Sciences
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2410071/
https://ncbi.nlm.nih.gov/pubmed/18093926
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0706407105
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