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Synthesis of the alkenyl-substituted tetracyclic core of the bisabosquals
HCl-catalyzed deprotection and cyclization of benzylic alcohol 15 cleanly provided tricycle 16 by a cis-selective intramolecular Diels-Alder reaction. Acetylation of the phenol, bis epoxidation, and base-catalyzed hydrolysis and cyclization afforded tetracycle 19 with the bisabosqual skeleton, but t...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2007
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2084385/ https://ncbi.nlm.nih.gov/pubmed/18836512 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2007.07.033 |
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